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Tverdye Elektrolity
Russian
129 b
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Monografiya posvyashchena issledovaniyu vazhneyshikh aspektov problemy tverdykh elektrolitov, a imenno: termodinamike obrazovaniya tverdykh elektrolitov (TEL); yavleniyu vysokovol'tnoy aktivatsii TEL; i kinetike formirovaniya dvoynogo elektricheskogo sloya na granitse blokirovannyy elektrod/tverdyy elektrolit v razlichnykh rezhimakh zaryazheniya. Termodinamicheskiy analiz baziruetsya na modelyakh kationnogo i anionnogo razuporyadocheniya TEL. Analiz yavleniya vysokovol'tnoy aktivatsii i effekta "pamyati" v TEL ob"yasnyayut s pozitsiy rosta podvizhnosti osnovnykh nositeley toka i uvelicheniya ikh kontsentratsii pod deystviem sil'nykh elektricheskikh poley. Pri provedenii kineticheskikh raschetov primenyayutsya kak relaksatsionnaya model' Grafova-Ukshe, tak i ekvivalentnaya model' Dzhekobsena i Vesta. Kniga rasschitana na nauchnykh sotrudnikov i spetsialistov, rabotayushchikh v oblasti fizicheskoy khimii i elektrokhimii tverdykh elektrolitov i rasplavlennykh soley, istochnikov i nakopiteley elektricheskoy energii, razrabotki novykh sistem preobrazovaniya, khraneniya i peredachi informatsii, a takzhe prepodavateley, studentov i aspirantov vuzov.
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