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Thermodynamically Self-consistent Integral Equation Theory

Name: Thermodynamically Self-consistent Integral Equation Theory
Brand: LAP Lambert Academic Publishing
SKU: 07091551
Price: 51.99 EUR
Availability: InStock
Author: R. C. Singh
ISBN: 9783659277252

Structure of Hard Ellipsoids of Revolution

R. C. Singh

Language

English

Book Paperback

Libristo code: 07091551

Publishers LAP Lambert Academic Publishing, November 2011

A thermodynamically self-consistent integral equation theory in which the hypernetted-chain (HNC) an... Full description

Libristo code: 07091551

127 b

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A thermodynamically self-consistent integral equation theory in which the hypernetted-chain (HNC) and Percus-Yevick (PY) approximations are mixed as a function of intermolecular separation for pair correlation functions of molecular fluids is described. This integral equation has been solved for a fluid of hard ellipsoids of revolutions (HER) of fixed geometry. Thermodynamic consistency between the virial and compressibility equation of state is achieved by varying a single parameter in a suitably chosen mixing function. When compared to available computer simulation data, the equation is found to yield excellent results for both the thermodynamic properties and the pair-correlation functions.