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Plasma Polymerization of Fluorocarbons and Polymer Surface Modification

Plasma Polymerization Behavior of Fluorocarbons in AC Discharges and Plasma Surface Modification of Polymers

Language EnglishEnglish
Book Paperback
Book Plasma Polymerization of Fluorocarbons and Polymer Surface Modification Mary Gilliam
Libristo code: 06946098
Publishers LAP Lambert Academic Publishing, November 2008
Plasma polymerization of fluorocarbons was investigated and compared to hydrocarbons. In fluorocarbo... Full description
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Plasma polymerization of fluorocarbons was investigated and compared to hydrocarbons. In fluorocarbon discharges, the plasma phase does not contain much polymer-forming species and the monomer deficient domain shifts to low W/FM and low GR/FM. The differences are attributed to the nature of fluorocarbons and the locations of the dissociation glow. In the second section, surface modification treatments were performed on seven polymers using low temperature cascade arc torch (LTCAT) of Ar with or without adding reactive gas of O2 or H2O. Static and dynamic surface characterization techniques were used to examine changes in wettability and surface stability and surface degradation. The surface stability induced from Ar LTCAT treatments was attributed to the CASING effect (cross linking via activated species of inert gas). Addition of O2 or H2O into Ar LTCAT resulted in greater wettability, but enhanced oligomer formation, which was more pronounced with H2O. The surface oligomer formation is attributed to alkoxy degradation reactions and enhanced chain scission.

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About the book

Full name Plasma Polymerization of Fluorocarbons and Polymer Surface Modification
Author Mary Gilliam
Language English
Binding Book - Paperback
Date of issue 2009
Number of pages 188
EAN 9783838324340
Libristo code 06946098
Weight 266
Dimensions 150 x 220 x 10
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